Electronic Conduction in Solid Nitrobenzene Containing Nitrobenzene Anion Radical and Tetrabutylammonium Perchlorate

Doped liquid nitrobenzene is ferroelectric.

The high resolution hyper-Rayleigh light scattering spectrum for liquid nitrobenzene doped with triflic acid (CF(3)SO(3)H) shows a narrow spike at zero frequency shift which has the polarization signature of a polar longitudinal collective mode. This spectral spike disappears for pure nitrobenzene. The spectral spike is interpreted as due to ferroelectric domains in the liquid. The dopant molec...

Hydrogenation of Nitrobenzene to Aniline

Photodissociation dynamics of nitrobenzene and o-nitrotoluene.

Photodissociation of nitrobenzene at 193, 248, and 266 nm and o-nitrotoluene at 193 and 248 nm was investigated separately using multimass ion imaging techniques. Fragments corresponding to NO and NO(2) elimination from both nitrobenzene and o-nitrotoluene were observed. The translational energy distributions for the NO elimination channel show bimodal distributions, indicating two dissociation...

Effects of Nitrobenzene and Benzene on Valonia

The effects of nitrobenzene and of benzene resemble those of guaiacol and of hexylresorcinol. The P.D. changes in a positive direction and then in a negative direction. The latter change may bring the P.D. back to the starting point with guaiacol and hexylresorcinol but with nitrobenzene and benzene this is not always the case. The positive potential change produced by nitrobenzene and benzene ...

Polar domain fluctuations in doped liquid nitrobenzene.

Improved spectral measurements of the narrow spike in the high resolution hyper-Rayleigh light scattering spectrum for deuterated liquid nitrobenzene (C(6)D(5)NO(2)) doped with triflic acid (CF(3)SO(3)H) determined that the reorientation time for the dopant-induced polar domains is 2.9 micros in the dilute limit. Two models based on ions dissolved in nitrobenzene fit the measured spectral broad...